o-38

(O-38)HEADSPACE ANALYSIS IN CHEMICAL ECOLOGY: UTILISING THERMAL AND SOLVENT DESORPTION OF POROUS POLYMERS

Nicky G. Agelopoulos

Biological and Ecological Chemistry Department, IACR-Rothamsted, Harpenden, Herts, AL5 2JQ, UK


Porous polymers (e.g. Porapak Q, Tenax TA) have been utilised extensively as pre-concentration techniques in chemical ecology. A comparative study was conducted to show the high sensitivity of thermal desorption vs. solvent elution of porous polymers. A number of examples will be presented to demonstrate that the polarity and quantity of solvent are crucial in eluting the trapped volatiles from the porous polymers. The advantages and disadvantages of thermal and solvent desorption in relation to chemical ecology studies will be discussed. Finally, an example of monitoring fast released compounds related to damage on potato leaves will be presented where both thermal and solvent desorption of polymers are used in a complimentary fashion.
N. Agelopoulos et al.1999. A novel approach for isolation of volatile chemicals released by individual leaves of a plant in situ. J. Chem. Ecol. 25(6): 1411-1425.


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